摘要:
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针对冷轧TRIP980钢表面色差缺陷,采用SEM、XRD等手段分析缺陷成因。结果表明:连续退火后板面色差位置呈现表层碎裂的形貌;能谱分析表明,与正常位置相比,缺陷位置存在明显的O元素峰,表现为Si、O元素的显著富集,与轧硬板的分析结果一致;XRD分析表明,热卷表面形成红色铁皮的原因是铁橄榄石类粘性氧化铁皮未能有效去除,导致后续轧制过程中形成了Fe2O3,由于在酸洗时效果不佳,冷轧后呈现表层碎裂的形貌,再经过连续退火,炉内还原气氛和高温导致Si、Mn等元素的富集,进而增加缺陷区域与正常区域颜色的衬度,最终表现为色差缺陷。由此可见,连续退火后表面色差是热轧、酸连轧等多道工序综合作用的结果。结合色差成因,通过优化板坯加热工艺,增强除鳞效果和酸洗能力,色差缺陷得到了有效控制。
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For surface color difference defects on cold-rolled TRIP980 steel,the causes of defects were analyzed through SEM and XRD methods. The results show that the area with color difference defects show the surface broken topography after continuous annealing. Through energy spectrum analysis, compared with normal position, an obvious O element peak is found and there is significant enrichment of Si and O elements in defect position, which is consistent with the analysis result of cold-rolled plate. Through XRD analysis, it is showed that the reason for red scales on the surface of hot coil is that the olivine cannot be removed effectively, resulting in the formation of Fe2O3 in subsequent rolling process. Broken topography on surface is formed after cold rolling because the red scale defect is difficult to be wiped off by pickling.After continuous annealing, the color contrast in the defect and normal areas increase to result in color difference defects finally because the reducing atmosphere and high temperature lead the enrichment of Si and Mn. Thus color difference defects after continuous annealing are the results of several processes, such as hot rolling and acid rolling.Based on the analysis of color difference defects, by optimizing the heating process of slab and enhancing the descaling effect and pickling ability, the color difference defect is controlled effectively.
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基金项目:
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作者简介:
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关晓光(1981-),男,硕士,副教授,E-mail:gxg_623@163.com;通讯作者:刘丽萍(1981-),女,硕士,高级工程师,E-mail:liulp2007@126.com
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参考文献:
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[1]李军,路洪洲,易红亮,等. 乘用车轻量化及微合金化钢板的应用[M]. 北京: 北京理工大学出版社,2015. Li J, Lu H Z, Yi H L, et al. Lightweight of Passenger Car and Niobium-microalloying Steel[M]. Beijing: Beijing Institute of Technology Press, 2015. [2]Powers W F. Automotive materials in the 21st century[J].Advanced Materials & Processes,2000, 157(5): 38-41. [3]Senuma T. Physical metallurgy of modern high strength steel sheets[J]. ISIJ International, 2001, 41(6): 520-532. [4]马鸣图.先进汽车用钢[M].北京:化学工业出版社,2007. Ma M T. Advanced Automotive Steel[M]. Beijing: Chemical Industrial Press, 2007. [5]徐斌,吝章国,贾耿,等. 汽车用冷轧板表面色差缺陷的研究[A].河北省2010 年炼钢-连铸-轧钢生产技术与学术交流会论文集[C]. 邯郸, 2010. Xu B, Lin Z G, Jia G, et al. Study on surface color difference defect of cold rolled plate for automobile[A].Proceedings of the Steelmaking-Continuous Casting-Rolling Steel Production Technology and Academic Exchange, Hebei Province 2010[C]. Handan, 2010. [6]刘晓程,张向东,孙学玉.冷轧板表面色差缺陷控制[J]. 河北冶金,2013,(11) : 60-61. Liu X C, Zhang X D, Sun X Y. Surface color difference control for cold-rolling sheet[J]. Hebei Metallurgical,2013, (11): 60-61. [7]郭晓波,钟莉莉,刘跃华. 冷轧板常见表面缺陷特征及成因分析[J]. 鞍钢技术,2011, (6): 37-42. Guo X B, Zhong L L, Liu Y H. Characteristics of common defects on the surface of cold-rolled sheet and analysis on causes leading to these defects[J]. Angang Technology, 2011,(6): 37-42. [8]左军,常军,刘勇,等. 热轧钢板红锈氧化铁皮形成机制及改进措施[J]. 钢铁,2010,45(10):84-87. Zuo J, Chang J. Liu Y, et al. Formation mechanism and improvement measures of red rust iron oxide skin of hot-rolled steel plate[J]. Iron and Steel, 2010, 45(10): 84-87. [9]蒋柯,韩静涛. 20MnSi氧化铁皮成分和结构研究[J]. 塑性工程学报,2000,7(3):40-43. Jiang K, Han J T. Scale component and microstructure of 20MnSi steel[J]. Journal of Plasticity Engineering, 2000, 7(3): 40-43. [10]王畅,于洋,潘辉,等. 高强机械用钢表面条带状红铁皮产生原因及机制[J]. 钢铁,2014,49(9):64-70. Wang C, Yu Y, Pan H, et al. Influencing factors and formation mechanism of banded red scale defect on hot rolled high strength steel strip surface for mechanical engineering application[J]. Iron and Steel, 2014, 49(9): 64-70. [11]张清东,王文广,吴越,等. 冷轧带钢板形和表面粗糙度协同控制[J]. 北京科技大学学报,2005,27(2):232-234. Zhang Q D, Wang W G, Wu Y, et al. Coordinated control of flatness and surface roughness on strip of 2030 mm cold tandem mills[J]. Journal of University of Science and Technology Beijing, 2005, 27(2): 232-234. [12]张亮亮,李研,于洋,等. 780 MPa级双相钢条状色差缺陷成因及改善措施[J]. 钢铁,2017,52(1):81-86. Zhang L L, Li Y, Yu Y, et al. Origin analysis and improvement measures for striped color defects of 780 MPa grade dualphase steel[J]. Iron and Steel, 2017, 52(1): 81-86.
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