锻压技术

热固性预浸料模压成型工艺参数实验研究

英文标题：Experimental study on compression molding process parameters for thermosetting prepreg

作者：孙奋丽郭平安边翊金康王小刚赵敏

单位：1.中机精密成形产业技术研究院（安徽）股份有限公司 2.北京机电研究所有限公司

分类号：TB332

出版年,卷(期):页码：2021,46(3):146-150

摘要：

通过研究热固性预浸料模压成型（Propreg Compression Molding, PCM）复合材料层合板制备过程中固化压力与树脂流失量之间的关系，对比不同树脂含量的预浸料在模压成型后的力学性能，发现最佳力学性能对应的预浸料树脂含量为38%。为了进一步提高PCM模压制品力学性能的稳定性，将模压后树脂含量保持在38%的固化压力作为固定参数，对模具温度和固化时间进行了16组正交实验，检测层合板的力学性能，并分析树脂与纤维织物界面之间的微观结合情况。结果表明：当固化压力为3800 kN时，可以将树脂含量为40%的预浸料在模压后的树脂含量控制在38%左右，并在模具温度为155 ℃、预热时间为40 s、保压时间为440 s时，得到抗拉强度为520.18 MPa、冲击韧性为32.35 J·cm-2、综合力学性能最好同时微观缺陷最少的样品。经现场工艺验证，实验得到的规律和工艺参数组合可应用于热固性复合材料汽车电池包上盖的批量生产中。

By studying the relationship between curing pressure and resin loss amount during the preparation of composite laminates by thermosetting prepreg compression molding (PCM), comparing the mechanical properties of prepregs with different resin contents after compression molding, the best mechanical properties were found that the corresponding prepreg resin content was 38%. In order to further improve the stability of mechanical properties for PCM molded products, taking the curing pressure when the resin content was maintained at 38% after compression molding as a fixed parameter, and sixteen sets of orthogonal experiments were carried out on the combination of mold temperature and curing time to detect the mechanical properties of laminate and analyze the microscopic bond conditions between resin and fiber fabric interface. The results show that when the curing pressure is 3800 kN, for the prepreg with a resin content of 40%, the resin content can be controlled at about 38% after compression molding, and when the mold temperature is 155 ℃, the preheating time is 40 s and the holding time is 440 s, a sample with the tensile strength of 520.18 MPa, the impact toughness of 32.35 J·cm-2 is obtained, which has the best comprehensive mechanical properties and the least micro defects. The on-site process verification shows that the law and process parameter combination obtained from the experiment can be applied to the mass production of automotive battery pack upper cover for thermosetting composite materials.

基金项目：

国家科技重大专项课题（2018ZX04001026）；科技部“科技助力经济2020”重点专项项目

孙奋丽(1995-)，女，硕士研究生 E-mail：384805944@qq.com 通讯作者：边翊(1976-)，男，硕士，研究员 E-mail：bianyi@brimet.ac.cn

参考文献：

[1]刘万双,魏毅,余木火.汽车轻量化用碳纤维复合材料国内外应用现状[J].纺织导报,2016，(5):48-52.

Liu W S, Wei Y, Yu M H.Application status of carbon fiber composite materials for automotive lightweight at home and abroad[J].The Textile Herald,2016，(5):48-52.

[2]马晓坤,杨晓峰,姜婧，等.热固性碳纤维预浸料用环氧类基体树脂[J].弹性体,2013,23(3):83-88.

Ma X K, Yang X F, Jiang J，et al.Epoxy matrix resin for thermosetting carbon fiber prepreg[J].Elastomer,2013,23(3):83-88.

[3]唐见茂.新能源汽车轻量化材料[J].新型工业化,2016,6(1):1-14.

Tang J M.Lightweight materials for new energy vehicles[J].New Types of Industrialization, 2016,6(1):1-14.

[4]李洺君,王明明,吕文静.汽车轻量化材料的应用及现状[J].时代汽车,2020，(8):31-33.

Li M J, Wang M M, Lyu W J.Application and status quo of lightweight materials for automobiles[J].Time Car,2020，(8):31-33.

[5]赵振.航天复合材料工艺数据库构建及典型工艺研究[D].大连：大连理工大学,2010.

Zhao Z.Construction of Technology Database of Aerospace Composite Materials and Research on Typical Technology[D].Dalian:Dalian University of Technology,2010.

[6]朱楠,彭德功,李军,等.复合材料模压成型工艺研究[J].纤维复合材料,2020,37(2):33-35.

Zhu N, Peng D G, Li J，et al.Research on the molding technology of composite material by die [J].Fiber Composites, 2020,37(2):33-35.

[7]GB/T 1447—2005,纤维增强塑料拉伸性能实验方法[S].

GB/T 1447—2005,Test method for tensile properties of fiber reinforced plastics[S].

[8]GB/T 1043.1—2008,塑料简支梁冲击性能的测定[S].

GB/T 1043.1—2008,Determination of impact performance of plastic simply supported beams[S].

[9]吴海亮.树脂含量对玻璃纤维增强环氧树脂复合材料力学性能的影响[J].天津科技,2017,44(7):21-22,26.

Wu H L.Effect of resin content on mechanical properties of glass fiber reinforced epoxy resin composites[J].Tianjin Science & Technology, 2017,44(7):21-22,26.

[10]李超,丘哲明,刘建超.树脂含量对碳布/环氧复合材料力学性能的影响[J].纤维复合材料,2003，(1):15-17.

Li C, Qiu Z M, Liu J C.Effect of resin content on mechanical properties of carbon cloth/epoxy composites[J].Fiber Composite,2003，(1):15-17.

[11]沃西源,薛芳,李静.复合材料模压成型的工艺特性和影响因素分析[J].高科技纤维与应用,2009,34(6):41-44.

Wo X Y, Xue F, Li J.Analysis of technological characteristics and influencing factors of composite molding [J].High-tech Fibers and Applications,2009,34(6):41-44.

[12]蔡烨梦,孙树凯.玻璃纤维预浸料制备板簧模压成型工艺研究[J].合成纤维工业,2018,41(6):31-35.

Cai Y M, Sun S K.Research on die forming technology of plate spring prepared with glass fiber prepreg [J].China Synthetic Fiber Industry,2018,41(6):31-35.

服务与反馈：

【文章下载】【加入收藏】